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Beilstein J. Org. Chem. 2020, 16, 1436–1446, doi:10.3762/bjoc.16.119
Graphical Abstract
Scheme 1: Schematic overview of the McKenna reaction including the decomposition of BTMS in protic solvents. ...
Figure 1: The model compounds used for this study (in red: the functionality of the molecules vulnerable to s...
Scheme 2: Formation of the side products derived from 10. Conditions: An equimolar mixture of propargylamide ...
Scheme 3: Addition of HBr to compound 11.
Scheme 4: N-Alkylation of 9.
Scheme 5: N-Alkylation of 12.
Scheme 6: Exchange of the chlorine substituent with bromine in 2-chloro-N-phenethylacetamide (13) under McKen...